Encapsulation of trivalent phosphate anion within a rigidified π-stacked dimeric capsular assembly of tripodal receptor.

نویسندگان

  • Sandeep Kumar Dey
  • Gopal Das
چکیده

The tris(thiourea) receptor, L, in the presence of excess H(2)PO(4)(-) has been found to encapsulate a trivalent phosphate ion within a π-stacked dimeric capsular assembly of the receptor with twelve strong H-bonds via deprotonation, as evident from the origin of a new set of signals in the (1)H NMR titration experiments.

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عنوان ژورنال:
  • Dalton transactions

دوره 40 45  شماره 

صفحات  -

تاریخ انتشار 2011